WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. (vii) for dangerous goods that are subject to special provision 23, the words toxic by inhalation or toxic inhalation hazard or toxique par inhalation or toxicit par inhalation; Examples of classification descriptions of dangerous goods are: UN1214, ISOBUTYLAMINE, Class 3, Subsidiary Class (8), II, UN1214, ISOBUTYLAMINE, Class 3(8), Packing Group II, UN3381, TOXIC BY INHALATION LIQUID, N.O.S., Class 6.1 PG I, UN 1075 LIQUEFIED PETROLEUM GASES (propane); Not odourized, Class 2.1. Please check if any of these measures apply to you. endobj a person capable of understanding the nature of the dangerous good (e.g., manufacturer's professional employees such as a chemical engineer, chemist, scientist, etc. TDG "Special Case and Special Provision Exemptions, NITROSTARCH, WETTED with not less than 20% water, by mass, ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. UN Dangerous Goods List 1. Admin. Dangerous goods safety marks are the first line of communication about the hazard(s) of the dangerous good. Being on this list does not mean Transport Canada or the TDG Directorate endorses or approves their services. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. If you have questions or need any help, please contact our sponsor. 12 Va. Admin. The labels must be displayed on two opposite sides of the outer surface of a small means of containment. The technical name shall be a recognized chemical or biological name, or other name currently used in scientific journals and handbooks. hazard class, classified in Class 6.1, Toxic substances that are listed in Special Provision 23, classified in Class 7, Radioactive materials that require a Cat III Yellow label. Powdered metals. ), MARINE POLLUTANT. Product mixture that consists of multiple dangerous goods: If the shipping name is not a specific name, then the technical name of the most dangerous substance needs to be provided in brackets as required in Special Provision 16 in Schedule 2. Relevant identified uses of the substance or mixture and uses advised against Intended use Application Method 1.3. Products and For hazardous mixtures or other articles, it takes more efforts and expertise to determine an accurate UN number and proper shipping name. Assigning a substance into a hazard class is usually done by the consignor. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. This requirement is outlined in Part 5 of the TDG Regulations. That legal outcome opened the door to hire a new design and construction team to finish the North Course. Electronic Code of Federal Regulations (e-CFR), Subtitle B - Other Regulations Relating to Transportation, CHAPTER I - PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION, SUBCHAPTER C - HAZARDOUS MATERIALS REGULATIONS, PART 172 - HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, TRAINING REQUIREMENTS, AND SECURITY PLANS, Ariz. Admin. For example, based on the above information from Schedule 1 we have the following information for UN1203: Schedules 1 and 3 will also indicate if any shipping routes are forbidden. Services Main Page. This document may be: The proof of classification must include the following information: The TDG Directorate keeps alist of laboratoriesthat provide dangerous goods analysis and classification. You need to ask yourself the following questions first and follow the above rules to determine accurate proper shipping names for your products. 13 020 - 13-020 - ADVANCE NOTIFICATION OF TRANSPORT OF NUCLEAR WASTE, 10A NCAC 15 .0346 - 10A NCAC 15 .0346 - PREPARATION OF RADIOACTIVE MATERIAL FOR TRANSPORT. Code R. Ch. Initial boiling point is greater than 35C at an absolute pressure of 101.3 kPa. Mercury If the product's name (e.g., chemical name) is listed in Schedule 1 or 3 then the primary hazard class is in Column 3 of Schedule 1 and in Column 2 of Schedule 3 for that shipping name. Flammable solids 5. For hazardous materials transported by sea with a flash point at or below 60 clesius degrees, the IMDG Code requires an indication of the flash point after the proper shipping name. Specific chemical name (e.g., acetone, sulfuric acid, etc. Mercury also combines with carbon to make organic mercury compounds. Note 3: The containers inside the package not required to bear TDG safety marks. Information on compatibility groups is provided in Appendix 2 of Part 2 in the TDG Regulations. View Past Newsletter, Class 4 Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases, Class 5 Oxidizing substances and organic peroxides, Class 9 Miscellaneous dangerous substances and articles, including environmentally hazardous substances, Biocides and Biocidal Product Regulations, I (High Danger) > II (Medium Danger) > III (Low Danger), Materials of class 7 (except radio-active materials in excepted packages), Liquid desensitised explosives of class 3, Self-reactive substances and solid desensitised explosives of division 4.1, Substances of division 6.1 or class 3 with packing group I by inhalation. Note: The information below is provided as guidance only. This mark is displayed on small means of containment filled with infectious substances that are assigned to UN3373, Biological Substance Category B. Self-heating solid, toxic, organic, n.o.s. Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. What types of other dangerous goods safety marks may be required? The required markings for overpacks include: Placards are not required for consolidation bins as the definition and description for a consolidation bin does not include large means of containment. That legal outcome opened the door to hire a new design and construction team to finish the North Course. However, if the product's name is not listed in Schedule 1 or 3, then the product must be tested at a laboratory. It is required that proper shipping names be supplemented with the technical or chemical group name. For more details, consult the legislation directly. When test results and the hazard class criteria are compared, there are three possible conclusions: a) The laboratory test results show the product does not meet any of the criteria for the hazard classes. Wastes: Make sure the appropriate labels (TDG or Workplace Hazardous Materials Information System (WHMIS) are used in the workplace as required. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. Dangerous goods that can be shipped under this exemption will have an excepted quantity code of E1, E2, E3, E4, or E5 in Column 6(b) of Schedule 1 of the TDG Regulations. The following state regulations pages link to this page. For example, both gasoline and diesel are listed by their name in Schedule 1. In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. They are preferred in the following order: If you cannot find a good match in 1, you move to 2, 3 and 4 by order. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. The main product line is outboard motors. The labelling requirements for an overpack depend on whether the labels can be seen through the overpack. It can be either a tag or a fixed display device (white board or a piece of paper) that will be updated every time a dangerous good is removed or added (Section 4.10.2 in the TDG Regulations). There are 4 types of entries consisting of UN numbers and proper shipping names in the The following provisions also apply: (i) For empty uncleaned packaging, only the number and type of packaging must be shown; (ii) For chemical kits and first aid kits, the total net mass of hazardous materials must be shown. See Section 4.23 of Part 4 in the TDG Regulations. Meanwhile the actual assigned category is obtained from Appendix 3 in Part 2. (v) the subsidiary class or classes, in parentheses, which may be shown as a number only or under the heading subsidiary class or classe subsidiaire or following the words subsidiary class or classe subsidiaire, except that, for transport by aircraft or by ship, the subsidiary class or classes may be shown after the information required by this paragraph, (vi) the packing group roman numeral, which may be shown under the heading PG or GE or following the letters PG or GE or following the words Packing Group or Groupe d'emballage, and. symbol (e.g., explosion, flames, corrosion, etc. You can download all hazard symbols for all hazard classes above by clicking the picture below. : M141-1LB; M141-6LB Synonyms Colloidal mercury; Hydrargyrum; Metallic mercuryRecommended Use However, it would be prudent to hire a laboratory with appropriate accreditations. b) The laboratory test results show the product falls into one class and one packing group. Elevated temperature solid, n.o.s., at or above 240C (464F). Admin. WebEach subsidiary must be associated with at least one nexus. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. WebEU mercury 7439-97-6 IOELV 0,02 2009/ 161/EU IE mercury 7439-97-6 OELV 0,02 S.I. How do I assign Categories A and B for the infectious substances? Although there are different degrees of separation of dangerous goods The classification or shipping description is reported in the following order as per Part 3.5: (ii) the shipping name and, immediately after the shipping name unless it is already part of it, (a) for dangerous goods that are subject to special provision 16, the technical name, in parentheses, of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods, and. Read More: Marine Pollutants & Environmentally Hazardous Substances: Definition, Marking and Exceptions. Placards are not required or are optional for some dangerous goods when the gross quantity of the dangerous goods is 500 kg or less. Trade name is not accepted. There may be occasions when several different shipping names can be used. Generally, the shipping name should be selected in the following hierarchical order: 1. WV Code Reg. will be unavailable during this time. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM Where or how do I find the above information? Alkalis. Rules 007-001-RH-3509 - RH-3509 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste. What safety marks are required on a small means of containment (capacity 450L or less)? Example: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 220 M - SUBPART M - REPORTS, 105 Mass. Code tit. Figure 4: Placard requirements and placement for compartmentalized means of containment. The labels must be displayed on any side of the outer surface of a means of containment other than the side on which it is intended to rest or be stacked during transport. Where can I get my product analyzed for classification? Subsidiary Classes Access to this website :), How to Assign UN Packing Group for Dangerous Goods. Used to display the UN number on a large means of containment (greater than 450 L) when the UN number is not included in the hazard class placard. But a sealed glass ampule holding mercurywhen the ampule is in the form of a long cylinder with lines marked on the side for measuring temperatureis a thermometer, a mercury article, and would be shipped as "UN 3506, MERCURY 28-35-189a - 28-35-189a - Advance notification of transport of nuclear waste, Kan. Admin. Depending on the classification for a dangerous good, one or more of the following safety marks may be required on a large means of containment: NOTE: Generally speaking, a placard must be displayed for each of the dangerous goods transported in a large means of containment regardless of the quantity. ; UN 1224, KETONES, LIQUID, N.O.S, Example: UN 1993 FLAMMABLE LIQUIDS, N.O.S. Please also see the following documents in this series: The purpose of dangerous goods safety marks is to: Dangerous goods safety marks are required when the good that is being transported: The TDG Regulations (Part 4) specify that all safety marks must be: Responsibilities for dangerous goods safety marks depend on whether the handler of the dangerous goods is the: Before the goods are loaded on the means of transport (i.e., vehicle, truck), the consignor or importer must: Misleading safety marks are dangerous goods safety marks that might be deceptive, ambiguous, or provide false information about the presence or nature of any dangers. However, the mixture could no longer be described as "Gasoline" or "Diesel" since it would no longer have a specific name in Schedule 1. For transport from the United States into Canada by road vehicle or railway vehicle, the shipping name used must be one that is recognized in Schedule 1 of the TDG Regulations or in the UN Recommendations. The data below is an example showing UN1203, GASOLINE. Transportation of Dangerous Goods (TDG) - Dangerous Goods Safety Marks (Road), All Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. For example, for a flammable mixture consisting of two or more alcohols, both entries below may be applicable. Methylmercury and other organic compounds. Dangerous Goods of Class4.2, Packing Group III, not listed above, Magnesium powder or Magnesium alloys, powder, Dangerous Goods of Class4.3, Packing Groups I, not listed above, Aluminum smelting by-products or Aluminum remelting by-products, Phosphorus pentasulphide, free from yellow and white phosphorus, Dangerous Goods of Class4.3, Packing Groups II, not listed above, Calcium cyanamide, with more than 0.1% Calcium carbide, Ferrosilicon, with 30% or more but less than 90% silicon, Magnesium granules, coated, particle size not less than 149mm, Dangerous Goods of Class4.3, Packing Group III, not listed above, Ammonium nitrate, liquid, hot concentrated solution, Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide, Dangerous Goods of Class5.1, Packing Group I, not listed above, Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water, Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts, Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary, Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary, Potassium nitrate and sodium nitrite mixture, Dangerous Goods of Class5.1, Packing Group II, not listed above, Dangerous Goods of Class5.1, Packing GroupII, Solids, not listed above, having no subsidiary class other than Class9, Dangerous Goods of Class5.1, Packing GroupIII, Liquids, Dangerous Goods of Class5.1, Packing GroupIII, Solids, Dangerous Goods of Class5.2, Packing GroupI, Dangerous Goods of Class5.2, Packing GroupII, Dangerous Goods of Class5.2, Packing GroupIII, Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide, Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide, Hydrogen cyanide, stabilized, containing less than 3% water, Methyl bromide and ethylene dibromide mixture, liquid, Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23C (73F), Toxic by inhalation, liquid, n.o.s., with an LC, Toxic by inhalation, liquid, flammable, n.o.s., with an LC, Toxic by inhalation, liquid, water reactive, n.o.s., with an LC, Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC, Toxic by inhalation, liquid, corrosive, n.o.s., with an LC, Dangerous Goods of Class6.1, Packing GroupI, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupI, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, not listed above, with a subsidiary classification other than 9, Chlorosulphonic acid, with or without sulphur trioxide, Hydrazine, aqueous solution, with more than 37% hydrazine, by mass, Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass, Hydrofluoric acid and sulphuric acid mixture, Hydrofluoric acid solution, more than 60% hydrogen fluoride, Nitrating acid mixtures, more than 50% nitric acid, Nitric acid, other than red fuming, with more than 70% nitric acid, Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide, Sulphuric acid, fuming, less than 30% free sulphur trioxide, Dangerous Goods of Class8, Packing GroupI, not listed above, Battery fluid, acid or Sulphuric acid, with not more than 51% acid, Formic acid, with more than 85% acid by mass, Hydrofluoric acid solution, not more than 60% hydrogen fluoride, Nitrating acid mixtures, not more than 50% nitric acid, Nitric acid, other than red fuming, with not more than 70% nitric acid, Dangerous Goods of Class8, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class8, Packing GroupII, Solids, not listed above, Dangerous Goods of Class8, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class 8, Packing Group III, Solids, not listed above, Dangerous Goods of Class9, Packing GroupI, Liquids, Dangerous Goods of Class 9, Packing Group I, Solids, Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite), Dangerous Goods of Class9, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class 9, Packing Group II, Solids, not listed above. Classification can be done by a consultant or a competent employee who has been trained in TDG classification. The class posing a lower hazard will be identified as a subsidiary class. Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. Example 1: UN 1993, FLAMMABLE LIQUID, N.O.S (contains methanol and acetone); Example 2: UN 2902, PESTICIDE, LIQUID, TOXIC, N.O.S. Nitrites and their mixtures. What are the requirements for dangerous goods safety marks when displayed on the means of containment. White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. Mercury is an element and a metal that is found in air, water, and soil. Generic risk (e.g., flammable, toxic, etc.). This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. This mark is required when shipments meet the excepted quantity exemption. See Section 1.17.1 in the TDG Regulations. sponsor this page to leave your contact info on this page.. Mercury and its compounds. Flammable solid, corrosive, organic, n.o.s. For example, UN2744, Cyclobutyl chloroformate, 6.1, (8, 3), PG II. Shipping descriptions for hazardous materials offered or intended for transportation by rail that contain all the information required in this subpart and that are formatted and ordered in accordance with recognized electronic data interchange standards and, to the extent possible, in the order and manner required by this subpart are deemed to comply with this paragraph. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. SAFETY DATA SHEET - Fisher Sci Transportation of Dangerous Goods (TDG CHLORINE DIOXIDE is an example of a product that is forbidden by all routes of transportation as indicated in Schedule 3 with an entry of Forbidden in Column 2 - Hazard Class. Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. WebClass 3 material except PG I materials with a subsidiary hazard and UN1204, UN2059, UN3064, UN3256, UN3269 (unless authorized under SP A163), UN3357, UN3379, and UN3474 Division 4.1 PG II and PG III materials except UN2304, UN2448, UN2555, UN2556, UN2557, UN2907, UN3176, UN3221 through UN3240, UN3319 and UN3344 International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. Appendix E: Schedule 2 - List of Dangerous Goods Yes. If you are a consultant, you may get yourself listed in CSP business directory (free) or Download the OSH Answers app for free. NOTE: This category B mark must be displayed instead of the Class 6.2 label. Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. Basic Information about Mercury Mercury. How to Ship Hazmat with No Packing Group | Lion Technology Selecting a correct proper shipping name is not easy. 33, Part XV, 1519 - 1519 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste [Formerly 1516], 10 144 Me. Although a consignor may also use the classification of the manufacturer or a previous consignor, the consignor is still responsible for making sure the classification is correct, and for making a proof of classification available to the Minister. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. WebSubsidiary Hazard Class6.1 Packing Group III IMDG/IMO UN-No UN2809 Proper Shipping Name Mercury Hazard Class 8 Subsidiary Hazard Class6.1 Packing Group III 15. Mercury Factsheet | National Biomonitoring Program | CDC `9yYcQKL U\ >5Iy+&1fXM+DD.> vl=|TOZg]-L8o1016&nY#Xh*4z5tGLUlWi. Definition for a mixture a product that contains two or more ingredients. Examples of such products are: 3. Always check the TDG Act and Regulations to ensure compliance. WebMercury rarely occurs uncombined in nature, but can be found as droplets in cinnabar (mercury sulfide) ores. WebIdentification Product Name Mercury (Certified ACS) Cat No. 0 Note that the, classification (primary and subsidiary hazard classes), whether or not they are shipped under a TDG exemption, Label for the primary hazard class for each dangerous good in the package, Label for the subsidiary hazard class (if any) for each dangerous good in the package, Shipping name and technical name when required in Special Provision 16 in Schedule 2 of the TDG Regulations. Class1.1, 1.2, 1.3 or 1.5 explosives that are: not subject to Special Provision 85 or 86 and the quantity is less than or equal to 10 kg, or, subject to Special Provision SP 85 or 86 and the quantity is less than or equal to 1000 articles (note: this is number of articles, not mass), Class 1.4 (except Class 1.4S) is 1000 kg or less, Class 6.1 and are not required to comply with Special Provision 23, Class 6.1 but are not an inhalation hazard and are not listed in Special Provision 23. capacity of each cylinder is greater than 225 L, are interconnected through a piping arrangement, and, are permanently mounted on a structural frame for transport, Class 6.1 for exposure to other routes (not an inhalation hazard)and are not listed in Special Provision 23, Class 6.1, Toxic Substances due to inhalation toxicity, Are dangerous goods subject to Special Provision 23. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. See Section 4.10(5) in the TDG Regulations for circumstances when labels are not required and the "Packaging and Transport of Nuclear Substances Regulations" for specific marking requirements. Founded in 1961 and headquartered in Los Angeles, Mercury has assets in excess of $4 billion, employs 4,500 people and has more than 8,000 independent agents in 11 states (Arizona, California,
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